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Liko, a girl from the Paldea region, enrolls in a boarding school in Kanto.

Liko and Sprigatito are taken to an Airship, where they are introduced to the Rising Volt Tacklers.

After Sprigatito is taken by Amethio's group, Liko works alongside Friede to plan a rescue.

When the airship makes an emergency landing, the ship's Fuecoco disappears. Meanwhile, islander Roy witnesses a mysterious Pokémon.

To meet Fuecoco, Roy must go to the Rising Volt Tacklers' airship. Meanwhile, the Explorers' submarine approaches the airship.

When the Explorers land on the Island, Liko and Roy must work together as a team in order to defeat them.

As the Rising Volt Tacklers' journey continues through the skies, Liko and Roy decide to train under Captain Pikachu in order to get better at Pokémon battling. Neither Sprigatito nor Fuecoco are even remotely a match for the overwhelmingly strong Cap, but the training makes Liko realize something.

The Rising Volt Tacklers' airship faces a food shortage. Suspecting someone is secretly overeating, the crew splits up to go shopping while Liko guards the ship and uncovers a secret.

The Rising Volt Tacklers arrive in Paldea, where Liko reunites with her father, Alex. As Liko settles at home, Alex unexpectedly asks her to stay permanently, potentially ending her journey before it truly begins.

Alex, Liko's father, leads them to Artazon's closed Gym. Stumped, a Champion aids them by taking Liko and Roy to Brassius' atelier.

A burnt forest conceals an untouched area where Liko, Roy, Brassius, and Molly travel after a Shiny Rayquaza sighting. Hostile Arboliva obstruct their investigation into the blaze's origin.

Rarecoil's interference is eliminated, allowing recruitment of Landau to irrigate soil with his Nuoh. Oliva can then fully restore greenery in a damaged forest.

The Rising Volt Tacklers experience control system issues on their airship during their trip to Galar to see Liko's grandmother. To pass time, they picnic, with Liko joining in sandwich-making while fretting over Dot, who remained aboard.

Roy and Fuecoco go to see a peculiar Wattrel that isn't with its flock. Once Roy discovers that Wattrel can't fly, he offers to help it. Will Wattrel be able to fly to be with its flock or will it decide to find its own path?

Liko suddenly goes missing while out shopping. The Rising Volt Tacklers search Artazon for her based on reports on her whereabouts Dot has gathered through the Internet, but are unable to locate her. As the group grows increasingly nervous, sensing the involvement of an enemy they can't see, Dot plays her trump card and contacts Iono, popular streamer and Gym Leader of Levincia City.

Liko's pendant has been stolen, and the Rising Volt Tacklers have set off to retrieve it. But then the Ancient Monster Ball Arboliva went into starts shining, and the light leads the group to an unknown destination?

Kaiden and Hogator are constantly fighting, and it really bothers Roy that they aren't getting along. He thinks about how they might bond by battling together against Captain Pikachu.

The Rising Volt Tacklers return to the Galar Mine in their search for the Black Rayquaza. As they search the area, Liko and Roy get separated from Friede, and continue deeper into the mine when they hear a mysterious cry. There, they find a group of people and Pokémon that have somehow completely lost their spirit and vigor. Meanwhile, Amethio and his Explorer companions also arrive at the mine in pursuit of Rayquaza.

Liko and Roy ask Friede about his past in order to get closer to Cap. And so the fateful encounter between Friede and Captain Pikachu is finally revealed.

The group has arrived in the Galar region, where they decide to leave the conspicuous airship behind and travel by land to the old castle Liko's grandmother Diana is supposed to be in. However, since the train is currently out of service, they decide to spend some time in Motostoke, where Liko and Roy head for the Battle Café alongside the Rising Volt Tacklers' cook, Murdock. There, they encounter Mitchell, a patissier and former colleague of Murdock's. And it seems the two have quite the history.

Liko and Roy have met Kabu, the Gym Leader of Motostoke Stadium and a native of the Hoenn region. Figuring that this means he might know something about Rayquaza, the Legendary Pokémon that's likewise from the Hoenn region, they decide to ask him about it. Kabu is so moved by their dedication he decides to train them. It's time for Kabu's fire training to begin.

The information they received from Kabu sends Liko, Roy and the others to the Galar Mine in search of the Black Rayquaza. On the way, they find an unconscious Hatenna, which Mollie diagnoses to be "suffering emotionally"; in other words, having been injured from constantly picking up emotions from nearby creatures. Unwilling to just leave her there, Liko decides to look after her on her own, but.

What the group found in the Galar Mine was a Galar Fire. Liko and the others want to close in on this Galar Fire, but it's burning with anger and keeps everyone at arm's length. What is the plan they come up with that incorporates Kabu's advice?.

Liko, Roy and Friede head for Galar's ancient castle. Guided by Diana's Squawkabilly, they arrive at an old castle where Liko is finally reunited with Diana, her grandmother.

Liko, Roy and Friede have gone to the old castles in the Galar region to meet with Diana. Amethio arrives there too, but believe it or not, Sango and Onyx then show up and attack as well. Will Liko and Roy be able to protect Terapagos?